Product ID:POLY BD R-45M RESIN, S01104
MSDS Date:04/28/1989
FSC:8040
NIIN:00N039345
MSDS Number: BRLBQ

Emergency Phone: 215-582-1551;800-424-9300(CHEMTREC)

Info Phone: 800-328-2811;215-889-0217

Preparer: SAFETY & ENVIRON AFFAIRS

Cage: 58598

Telephone: 800-328-2811;215-889-0217

Cage: 58598

HYDROXY TERMINATED 1,3-BUTADIENE HOMOPOLYMER

CAS: 69102-90-5

Fraction By Weight: 99.9%

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:DIRECT CONTACT OR VAPORS MAY
CAUSE SLIGHT IRRITATION. SKIN:LIQUID MAY CAUSE SLIGHT IRRITATION.
INGEST/INHAL:NO DATA CONCERNING ACUTE HEALTH EFFECTS VIA
INGEST/INHAL HAVE BEEN IDENTIFIED. CHR ONIC:NO EFFECTS FROM
EXPOSURE ARE KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:AS W/OTHER ORGANIC SOLVENTS,
EXPOSURE MAY AGGRAVATE PRE-EXISTING CONDITIONS SUCH AS COLDS,
ALLERGIES, ASTHMA, EMPHYSEMA, PSORIASIS & LOW BLOOD PRESSURE.

First Aid:EYES:IMMEDIATLEY FLUSH W/FLOWING WATER FOR AT LEAST 15
MINUTES. SEE MD IF IRRITATION PERSISTS. SKIN:REMOVE CONTAMINATED
CLOTHING & WASH EXPOSED SKIN W/LARGE AMOUNTS OF WATER. SEE MD IF
IRRITATION PERS ISTS. INGEST:SEE MD IF IRRITATION PERSISTS.
INHAL:IF PROBLEM DEVELOPS, REMOVE PERSON TO FRESH AIR & SUPPLY
OXYGEN IF NECESSARY.

Flash Point Method:TOC
Flash Point:>400F,>204C
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MOVE CNTNR FROM FIRE AREA IF POSS. COOL
FIRE EXPOSED CNTNRS W/WATER WELL AFTER FIRE IS OUT TO PVNT POSS
EXPLOS. HEAT FROM FIRE CAN GEN FLAMM VAP THAT IS(SUPDAT)

Spill Release Procedures:VENTILATE AREA & REMOVE ALL IGNITION SOURCES.
CONTAIN SPILL BY BUILDING DIKE USING ABSORBENT MATERIAL. COLLECT
REMAINDER OF SPILL W/ABSORBENT MATERIAL & PLACE MATERIAL INTO DRUM
APPROVED FOR WASTE DIS POSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MINIMIZE VAPORIZATION BY SEALING IN
TIGHTLY CLOSED CONTAINER. STORE IN COOL, WELL-VENTILATED AREA. KEEP
AWAY FROM HEAT, SPARKS & OPEN FLAMES.
Other Precautions:AVOID EYE & SKIN CONTACT. WHEN TRANSFERRING FROM
CONTAINERS, GROUND & BOND BOTH CONTAINERS.

Respiratory Protection:FOR CNDTNS WHERE EXPOS TO DUST & FUMES IS
APPARENT, A NIOSH/MSHA APPRVD RESP FOR DUST MISTS & FUMES APPROP TO
AIRBORNE CONC MAY BE WORN. WHERE VAPS ARE GENERATED, A NIOSH/MSHA
APPRVD ORGANIC RESP SUIT ABLE TO AIRBORNE CONCS IS RECOMMENDED.
Ventilation:PROVIDE LOC EXHST VENT WHERE HEAT CAN CAUSE POLYMER
BREAKDOWN, E.G. EXTRUSION, MOLDING & WHERE THERE IS NEED TO
(SUPDAT)
Protective Gloves:NITRILE (NBR) OR NATURAL RUBBER.
Eye Protection:SPLASH PROOF GOGGLES W/SIDE SHIELDS.
Other Protective Equipment:USE NITRILE (NBR) OR NATURAL RUBBER. WEAR
IMPERVIOUS BODY COVERING & BOOTS WHERE SPILLS OR SPLASHING OCCUR.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:HVR/AIR. HAZ COMBUST PRODS:SMALL QTYS OF BUTADIENE, ALONG
W/OXIDES OF CARBON. VENT:DRAW DUSTS & FUMES FROM WORKER BREATHING
ZONES. FOLLOWING PUBLICATION OFFERS VENT GUIDELINES & TECHNIQUES:
"INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED PRACTICE."
AVAILABLE FROM ACGIH.

Boiling Pt:B.P. Text:572F,300C
Spec Gravity:0.90
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; MILD HYDROCARBON ODOR.

Stability Indicator/Materials to Avoid:YES
ACIDS & STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, OPEN FLAME, PROLONGED STORAGE AT
ELEVATED TEMPERATURES.
Hazardous Decomposition Products:OXIDES OF CARBON & BUTADIENE.

Waste Disposal Methods:DISPOSE OF SOLID WASTE AT PROPERLY PERMITTED
LANDFILLS OBSERVING ALL LOCAL, STATE & FEDERAL REGULATIONS. CONTAM
LIQUIDS SHOULD BE CONCENTRATED & INCINERATED AT PROPERLY PERMITTED
DISP SITE AGAIN OBSER VING ALL LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.